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intermediate · Physics · Addition of Angular Momenta

Singlet and Triplet States

Splitting four states into 3 + 1

Two spin-12\tfrac12 particles live in a four-dimensional space. The previous lesson showed that the aligned state  ⁣|\!\uparrow\uparrow\rangle has total spin s=1s = 1. The full space organizes into a triplet (s=1s=1, three states) and a singlet (s=0s=0, one state). The names count the 2s+12s+1 values of mm in each family.

The triplet (s=1s = 1)

The three triplet states are symmetric under exchange of the two particles:

1,+1= ⁣,1,0=12( ⁣+ ⁣),1,1= ⁣.\begin{aligned} |1, +1\rangle &= |\!\uparrow\uparrow\rangle, \\ |1, 0\rangle &= \tfrac{1}{\sqrt{2}}\big(|\!\uparrow\downarrow\rangle + |\!\downarrow\uparrow\rangle\big), \\ |1, -1\rangle &= |\!\downarrow\downarrow\rangle . \end{aligned}

We can see how the middle state arises by applying the total lowering operator S=S1+S2S_- = S_{1-} + S_{2-} to the top state 1,+1= ⁣|1,+1\rangle = |\!\uparrow\uparrow\rangle:

S ⁣=(S1 ⁣) ⁣+ ⁣(S2 ⁣)=( ⁣+ ⁣).S_-\,|\!\uparrow\uparrow\rangle = (S_{1-}|\!\uparrow\rangle)|\!\uparrow\rangle + |\!\uparrow\rangle(S_{2-}|\!\uparrow\rangle) = \hbar\big(|\!\downarrow\uparrow\rangle + |\!\uparrow\downarrow\rangle\big).

Normalizing gives exactly 1,0|1,0\rangle above. Applying SS_- once more lands on  ⁣=1,1|\!\downarrow\downarrow\rangle = |1,-1\rangle. All three share S2=22\mathbf{S}^2 = 2\hbar^2.

The singlet (s=0s = 0)

The remaining, antisymmetric combination is orthogonal to the triplet's m=0m=0 member:

0,0=12( ⁣ ⁣).|0, 0\rangle = \tfrac{1}{\sqrt{2}}\big(|\!\uparrow\downarrow\rangle - |\!\downarrow\uparrow\rangle\big).

Acting with S2\mathbf{S}^2 gives zero: it has total spin s=0s = 0, the unique state with no total angular momentum at all. Swapping the two particles multiplies the singlet by 1-1, in contrast to the symmetric triplet.

Why the singlet is special

Because 0,0|0,0\rangle carries zero total angular momentum and is rotationally invariant, it looks the same along every axis: measuring the two spins along any common direction always yields opposite results. This perfect anticorrelation is the heart of the Einstein–Podolsky–Rosen setup and of Bell-inequality tests.

Try it

Build the singlet 0,0=12(0110)|0,0\rangle = \tfrac{1}{\sqrt2}(|01\rangle - |10\rangle) as a two-qubit statevector. Remember qubit 0 is the left bit, so the amplitude is +12+\tfrac{1}{\sqrt2} on 01|01\rangle and 12-\tfrac{1}{\sqrt2} on 10|10\rangle.

Run your code to see the quantum state.

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