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intermediate · Physics · The Variational Method & WKB

WKB Quantization

A bound state must fit smoothly between its two classical turning points. WKB turns this "fitting" requirement into a precise condition on the accumulated phase — the Bohr–Sommerfeld quantization rule — which produces approximate (and sometimes exact) energy levels.

The phase-fitting condition

Between two turning points x1x_1 and x2x_2 the WKB wavefunction oscillates with the local momentum p(x)=2m[EV(x)]p(x) = \sqrt{2m[E - V(x)]}. For the wavefunction to match the decaying exponentials in the forbidden regions on both sides, the connection formulas (covered later) require the total phase swept between the turning points to equal a half-integer number of half-cycles. The result is

x1x2p(x)dx=(n+12)π,n=0,1,2,\int_{x_1}^{x_2} p(x)\,dx = \left(n + \tfrac{1}{2}\right)\pi\hbar, \qquad n = 0, 1, 2, \dots

The integer nn counts the nodes; the +12+\tfrac{1}{2} is the Maslov correction, contributing π/4\pi/4 of phase from each soft turning point. (For a hard wall the correction at that wall changes.)

Equivalently, in terms of the closed classical orbit in phase space,

pdx=(n+12)h,\oint p\,dx = \left(n + \tfrac{1}{2}\right)h,

which is the historical Bohr–Sommerfeld statement: the enclosed phase-space area is quantized in units of Planck's constant.

Applying it to the harmonic oscillator

Take V(x)=12mω2x2V(x) = \tfrac{1}{2}m\omega^2 x^2, in natural units =m=ω=1\hbar = m = \omega = 1, so V(x)=x2/2V(x) = x^2/2. A particle of energy EE turns around where V=EV = E, i.e. at x=±ax = \pm a with a=2Ea = \sqrt{2E}. The momentum is p(x)=2Ex2p(x) = \sqrt{2E - x^2}, and the action integral is a standard one:

aa2Ex2dx=πE.\int_{-a}^{a} \sqrt{2E - x^2}\,dx = \pi E .

Setting this equal to (n+12)π(n + \tfrac{1}{2})\pi:

πE=(n+12)π        En=n+12.\pi E = \left(n + \tfrac{1}{2}\right)\pi \;\;\Longrightarrow\;\; E_n = n + \tfrac{1}{2}.

Restoring units, En=(n+12)ωE_n = (n + \tfrac{1}{2})\hbar\omega — the exact harmonic-oscillator spectrum.

Try it

Solve the quantization rule aa2Ex2dx=(n+12)π\int_{-a}^{a}\sqrt{2E - x^2}\,dx = (n + \tfrac12)\pi for the n=2n = 2 level and return the energy. You can integrate numerically and bisect on EE, or use the closed form πE=(n+12)π\pi E = (n+\tfrac12)\pi. Either way the answer is 2.52.5.

Run your code to see the quantum state.

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