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intermediate · Physics · The Hydrogen Atom in Depth

Checkpoint: Hydrogen in Depth

This checkpoint pulls together the quantitative tools of the module: the energy spectrum, ionization energies, and the counting of degenerate states. Work each piece, then combine them.

What you need

The spectrum. En=13.6eV/n2E_n = -13.6\,\text{eV}/n^2. The level n=2n=2 sits at E2=3.4eVE_2 = -3.4\,\text{eV}.

Ionization energy. Removing the electron means raising it to the unbound threshold E=0E = 0. The energy required from level nn is

In=0En=+13.6eVn2.I_n = 0 - E_n = +\frac{13.6\,\text{eV}}{n^2}.

So from the ground state I1=13.6eVI_1 = 13.6\,\text{eV}, and from n=2n=2, I2=3.4eVI_2 = 3.4\,\text{eV}.

Degeneracy. The number of distinct states at level nn, including the electron's two spin orientations, is

gn=2n2.g_n = 2n^2.

For n=2n = 2 this is g2=8g_2 = 8: one 2s2s orbital and three 2p2p orbitals, each holding two spins.

Putting it together

These two numbers describe two independent facets of the same level — its binding (an energy) and its multiplicity (a count). The exercise asks you to compute both for n=2n=2 and report their product, I2g2I_2 \cdot g_2, as a single check that you can produce each quantity correctly.

The takeaway

You now hold the core quantitative results of the hydrogen atom: a 13.6eV/n2-13.6\,\text{eV}/n^2 spectrum, +13.6eV/n2+13.6\,\text{eV}/n^2 ionization energies, and 2n22n^2-fold degenerate levels. Together they account for hydrogen's spectrum and the shell structure that organizes the periodic table.

Try it

This is a numerical exercise — return a number. For the n=2n=2 level, compute the ionization energy I2I_2 (in eV) and the total degeneracy g2=2n2g_2 = 2n^2 (including spin), then return their product I2g2I_2 \cdot g_2.

Run your code to see the quantum state.

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