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intermediate · Physics · Time Evolution & the Schrödinger Picture

Energy Eigenstates Evolve Simply

The last lesson built the general solution as a sum of phase-rotated eigenstates. Now we zoom in on the simplest possible case — a state that is an energy eigenstate — and see why such states barely change at all.

A single phase factor

Let ∣En⟩|E_n\rangle be an eigenstate of the Hamiltonian, H^∣En⟩=En∣En⟩\hat H|E_n\rangle = E_n|E_n\rangle. Applying the evolution operator is trivial because H^\hat H acts as a number on this state:

U(t)∣En⟩=e−iH^t/ℏ∣En⟩=e−iEnt/ℏ∣En⟩.U(t)|E_n\rangle = e^{-i\hat H t/\hbar}|E_n\rangle = e^{-iE_n t/\hbar}|E_n\rangle.

The only effect of time is to multiply the state by the unit-modulus complex number e−iEnt/ℏe^{-iE_n t/\hbar}. The "direction" of the state vector in Hilbert space never moves; only its phase winds around.

Why these are called stationary states

Because the change is a pure overall phase, every observable prediction is time-independent. For any observable A^\hat A,

⟨A^⟩(t)=⟨En∣e+iEnt/ℏ A^ e−iEnt/ℏ∣En⟩=⟨En∣A^∣En⟩,\langle \hat A\rangle(t) = \langle E_n|e^{+iE_n t/\hbar}\,\hat A\,e^{-iE_n t/\hbar}|E_n\rangle = \langle E_n|\hat A|E_n\rangle,

since the two scalar phases cancel. Measurement probabilities, expectation values — all frozen. An energy eigenstate prepared at t=0t=0 looks experimentally identical at every later time. This is why ∣En⟩|E_n\rangle is called a stationary state: nothing measurable evolves.

The phase still matters — eventually

Saying the phase is "invisible" is true only as long as the eigenstate stays alone. The moment you add a second component or interfere two copies of the system, the accumulated phase e−iEnt/ℏe^{-iE_n t/\hbar} becomes physical. So energy eigenstates are not boring — they are the carriers of phase information. The clock they carry, ticking at angular frequency En/ℏE_n/\hbar, is exactly what makes superpositions oscillate.

Try it

This is a numerical exercise — your code should return a number. The evolved amplitude of the eigenstate is e+iωt/2=cos⁡(ωt/2)+isin⁡(ωt/2)e^{+i\omega t/2} = \cos(\omega t/2) + i\sin(\omega t/2). Confirm stationarity by computing its modulus squared (the measurement probability), which must equal 11 for the arbitrary value ωt=1.234\omega t = 1.234.

Run your code to see the quantum state.

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