|q⟩ Bad Qubits

intermediate · Physics · Time Evolution & the Schrödinger Picture

Energy Eigenstates Evolve Simply

The last lesson built the general solution as a sum of phase-rotated eigenstates. Now we zoom in on the simplest possible case — a state that is an energy eigenstate — and see why such states barely change at all.

A single phase factor

Let En|E_n\rangle be an eigenstate of the Hamiltonian, H^En=EnEn\hat H|E_n\rangle = E_n|E_n\rangle. Applying the evolution operator is trivial because H^\hat H acts as a number on this state:

U(t)En=eiH^t/En=eiEnt/En.U(t)|E_n\rangle = e^{-i\hat H t/\hbar}|E_n\rangle = e^{-iE_n t/\hbar}|E_n\rangle.

The only effect of time is to multiply the state by the unit-modulus complex number eiEnt/e^{-iE_n t/\hbar}. The "direction" of the state vector in Hilbert space never moves; only its phase winds around.

Why these are called stationary states

Because the change is a pure overall phase, every observable prediction is time-independent. For any observable A^\hat A,

A^(t)=Ene+iEnt/A^eiEnt/En=EnA^En,\langle \hat A\rangle(t) = \langle E_n|e^{+iE_n t/\hbar}\,\hat A\,e^{-iE_n t/\hbar}|E_n\rangle = \langle E_n|\hat A|E_n\rangle,

since the two scalar phases cancel. Measurement probabilities, expectation values — all frozen. An energy eigenstate prepared at t=0t=0 looks experimentally identical at every later time. This is why En|E_n\rangle is called a stationary state: nothing measurable evolves.

The phase still matters — eventually

Saying the phase is "invisible" is true only as long as the eigenstate stays alone. The moment you add a second component or interfere two copies of the system, the accumulated phase eiEnt/e^{-iE_n t/\hbar} becomes physical. So energy eigenstates are not boring — they are the carriers of phase information. The clock they carry, ticking at angular frequency En/E_n/\hbar, is exactly what makes superpositions oscillate.

Try it

This is a numerical exercise — your code should return a number. The evolved amplitude of the eigenstate is e+iωt/2=cos(ωt/2)+isin(ωt/2)e^{+i\omega t/2} = \cos(\omega t/2) + i\sin(\omega t/2). Confirm stationarity by computing its modulus squared (the measurement probability), which must equal 11 for the arbitrary value ωt=1.234\omega t = 1.234.

Run your code to see the quantum state.

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