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beginner · Physics · The Wavefunction & Born Rule

Normalization of ψ

A wavefunction ψ(x)\psi(x) is only physically meaningful if the total probability of finding the particle somewhere equals exactly one:

ψ(x)2dx=1.\int_{-\infty}^{\infty} |\psi(x)|^2 \, dx = 1.

This requirement is called normalization. It follows directly from the Born rule: if ψ(x)2|\psi(x)|^2 gives the probability density, the entire probability density must integrate to one over all space.

The normalization constant

In practice, we often start with an unnormalized function ψ~(x)\tilde\psi(x) and write

ψ(x)=Aψ~(x),\psi(x) = A \, \tilde\psi(x),

where AA is a real positive constant chosen so that ψ\psi is normalized. Substituting:

ψ(x)2dx=A2ψ~(x)2dx=1A=1ψ~(x)2dx.\int |\psi(x)|^2 \, dx = A^2 \int |\tilde\psi(x)|^2 \, dx = 1 \quad \Longrightarrow \quad A = \frac{1}{\displaystyle\sqrt{\int |\tilde\psi(x)|^2 \, dx}}.

All that remains is to compute the integral of ψ~2|\tilde\psi|^2 and take the reciprocal square root.

A worked example

Consider the trial wavefunction defined on the interval [0,L][0, L]:

ψ~(x)=x(Lx),0xL,\tilde\psi(x) = x(L - x), \qquad 0 \le x \le L,

and ψ~=0\tilde\psi = 0 outside that interval. We need

0L[x(Lx)]2dx=0L(x2L22x3L+x4)dx.\int_0^L \big[x(L-x)\big]^2 dx = \int_0^L \big(x^2 L^2 - 2x^3 L + x^4\big) dx.

Integrating term by term:

=L2L332LL44+L55=L53L52+L55=L5(1015+630)=L530.= L^2 \cdot \frac{L^3}{3} - 2L \cdot \frac{L^4}{4} + \frac{L^5}{5} = \frac{L^5}{3} - \frac{L^5}{2} + \frac{L^5}{5} = L^5 \left(\frac{10 - 15 + 6}{30}\right) = \frac{L^5}{30}.

Setting L=1L = 1 gives the integral 130\frac{1}{30}, so the normalization constant is

A=11/30=30.A = \frac{1}{\sqrt{1/30}} = \sqrt{30}.

Substituting back confirms ψ(x)=30x(1x)\psi(x) = \sqrt{30}\, x(1-x) is normalized:

3001x2(1x)2dx=30130=1.30 \int_0^1 x^2(1-x)^2\, dx = 30 \cdot \frac{1}{30} = 1. \checkmark

Try it

This is a numerical exercise — your code should return a number. Given ψ(x)=Ax(1x)\psi(x) = A \cdot x(1-x) on [0,1][0, 1] and zero elsewhere, compute the positive normalization constant AA.

Run your code to see the quantum state.

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