Group and Phase Velocity
A quantum matter wave is rarely a single pure sinusoid. Instead, a localized particle is described by a wave packet: a superposition of sinusoidal components with wave-numbers spread around some central value . Two distinct speeds characterize how this packet moves.
Phase velocity
A single plane-wave component has a fixed phase on the surface . Solving for gives the phase velocity
For a free non-relativistic particle, the quantum mechanical dispersion relation follows directly from substituting the de Broglie relations and into the classical kinetic energy :
The phase velocity of each component is therefore
Notice that this equals half the classical particle speed . Individual plane-wave crests do not travel at the physically meaningful speed of the particle.
Group velocity
The group velocity is the speed at which the envelope — the overall shape of the wave packet — propagates. For a narrow packet peaked at it is
Differentiating the free-particle dispersion relation with respect to gives
This is precisely the classical particle velocity. The group velocity, not the phase velocity, carries the particle's energy and matches what a detector would record as the arrival time of the particle.
Dispersion
When depends on — equivalently, when — different frequency components travel at different speeds and the packet spreads over time. For the free-particle dispersion relation we have , so a free quantum wave packet always disperses (broadens) as it propagates. This spreading is a direct precursor to the Heisenberg uncertainty principle: a perfectly sharp position at requires a very broad superposition of momenta, and those momenta soon pull the packet apart.
Try it
This is a numerical exercise — your code should return a number. Use the free-particle dispersion
relation to compute the group velocity of an electron with wave-number
. The group velocity formula gives
; with and
this evaluates to approximately
.
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